Sunday, 20 February 2022

Kinetic Studies in the Oxidation of 2-aryl-3-Hydroxychromenones Using Sodium Hypochlorite (NaOCl) as an Oxidant | Chapter 07 | Challenges and Advances in Chemical Science Vol. 8

 


It has been reported that sodium hypochlorite (NaOCl) was used to oxidise 3-hydroxy flavone (3-HF) and 3-hydroxy-2-(thiophene-2-yl)-4H-chromen-4-one (THC). IR, 1H-NMR, and ESI-MS spectroscopic techniques were used to identify 3-hydroxy-2,3-dimethoxy-2-phenylchroman-4-one (1a) as the product of 3-HF in methanol (MeOH) as the solvent. There are no adverse effects in the production of this product. The yield of this product is close to 100%, as determined by isolating the product's absorption spectra from that of the reaction mixture in situ. THC, on the other hand, produces a dimeric compound after a comparable oxidation (2a). It has been proposed a process for the creation of 1a.

Author(S) Details

Kulvir Kaur
Department of Chemistry, Punjabi University, Patiala, Pin Code- 147002, India.

Gurmeet Kaur
Department of Chemistry, Punjabi University, Patiala, Pin Code- 147002, India.

Mandeep Kaur
Department of Chemistry, Punjabi University, Patiala, Pin Code- 147002, India.

Amandeep Kaur
Department of Chemistry, Punjabi University, Patiala, Pin Code- 147002, India.

Manisha Bansal
Department of Chemistry, Punjabi University, Patiala, Pin Code- 147002, India.

View Book:- https://stm.bookpi.org/CACS-V8/article/view/5631

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