Sustainable and Green Convergent Electro-Organic Synthesis of Substituted Benzyl Alcohol Derivatives in Biphasic Electrolysis | Chapter 12 | Progress in Chemical Science Research Vol. 7

 The growth of synthetically main free radical precursor from persulfate catalyst is an entertaining and wide-reaching urgent task. Persulfate mediated electro catalyzed oxidation of differing substituted benzyl alcohols in presence of water and dichloromethane gives functionalized scented benzaldehyde. In terms of green strength concern, electrochemical C-H activation has been acknowledged to be an adept strategy for the conversion of alcohols in appearance of H2S2O8/H2O system to give the scalable products accompanying high regioselectivity and in good to superior yields. The present work utilizes catalytic quantities completely scenarios and the selectivity is powerfully governed for one applied potential in a simple cup type electrolysis cell. In-situ create water soluble per sulfate radical in-between was well developed and a reasonable method was proposed exhaustive. Furthermore, the conversion of aryl alcohols to corresponding aldehydes was habitual by HPLC, 1H NMR and 13C NMR. This methodology facilitates work-up, atom economy and avoids the establishment of waste products.

Author(s) Details:

A. John Bosco,
Department of Chemistry, SRM Institute of Science and Technology, Kattankulathur, Chengalpattu District, Tamilnadu-603203, India.

R. Mohankumar,
Interdisciplinary Institute of Indian System of Medicine, Directorate of Research, SRM Institute of Science and Technology, Kattankulathur, Chengalpattu District, Tamilnadu- 603 203, India.

Please see the link here: https://stm.bookpi.org/PCSR-V7/article/view/10054