This review focuses on the electrochemical synthesis of intermetallic and refractory compounds in ionic melts using rare-earth metals, the iron triad, boron, and silicon. The widespread usage of rare earth metal-based magnets with record-high magnetic properties is impeded by their expensive cost, difficult manufacturing techniques, and the presence of rare metals. In chloride and chloride-fluoride melts, data on the electrochemical behaviour of lanthanides, iron, cobalt, and nickel chloride complexes, as well as fluoroborate and fluorosilicate ions are provided. Distinctive Characteristics ofThe electroreduction of rare-earth metal ions with iron triad ions, fluoroborate, and fluorosilicate ions is investigated. The ideal conditions for the electrosynthesis of rare-earth metal-based double and triple molecules are discussed. Future prospects for high-temperature rare-earth metal electrochemistry and technical solutions in the realm of electrosynthesis of rare-earth metal compounds in molten salts are discussed.
Author (S) Details
H. B. Kushkhov
Department of Inorganic and Physical Chemistry, Kabardino-Balkarian State University, 360004, 173 Chernyshevskogo Street, Nalchik, Kabardino-Balkaria, Russia.
M. R. Tlenkopachev
Department of Inorganic and Physical Chemistry, Kabardino-Balkarian State University, 360004, 173 Chernyshevskogo Street, Nalchik, Kabardino-Balkaria, Russia.
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