In the paper, a linear rule between osmotic coefficients on mole fraction base and each of several concentration expressions is presented, respectively, in single electrolyte solutions containing various valence inorganic acids, alkalies, and salts, such as uniuni-, biuni-, triuni-, tetrauni-, bibi-, and tribi-valence inorganic acids, alkalies, and salts. A thermodynamic model based on the rule is constructed and successfully used to these electrolyte solutions in order to predict and reproduce their traditional osmotic coefficients and other features. such as the decrease of relative molal vapour pressure, equivalent conductivity, solubility, and even ion interaction effects. The instances with positive outcomes have been provided.
Author (S) Details
Zheng Fang
Chemistry and Chemical Engineering College, Central South University, Changsha 410083, P.R. China.
View Book :- https://stm.bookpi.org/RTCAMS-V2/article/view/2914
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