Synthesis and Characterization of Cu(I) and Cu(II) Complexes Formed Through Carbon Disulfide Insertion | Chapter 14 | Current Advances in Chemistry and Biochemistry Vol. 6

 Two copper complexes [(PPh3)2Cu(S2COC2H5)] (A) and [(C3H4N2)2Cu(S2COC2H5)] (B) have been synthesized by the insertion of CS2 in (PPh3)2CuCl2 and (C3H4N2)2CuCl2, respectively in mixed At room temperature, a solvent of dichloromethane and ethanol. FTIR and ESR spectroscopy were used to characterize the complexes. Both complexes were discovered to be air-stable and to have distorted square planar geometry.

Author (S) Details

Samim Sultana
Department of Chemistry, Dibrugarh University, Dibrugarh-786004, Assam, India.

Prof. Pradip. K. Gogoi
Department of Chemistry, Dibrugarh University, Dibrugarh-786004, Assam, India.

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