In this phase, we provide the intrinsic definition of three key thermodynamic variables, building on prior theorizations of the systemic approach to open systems like soils. Temperature is delineated as the internal strength of the molecules that make up a fluid time ("α "); entropy is delineated as the ratio of two administrative variables of the phase ("the pertaining to work volume of molecules and their own book in the phase of book Vα; and the internal microscopic chemical potential is outlined as the ratio of a phase fragment's temperature to allure own mass. This admitted the following conceptual advances : i) beginning the definitional equations of the 3 equivalent forms of the Gibbs free energy of the liquid phase of the soil pedostructure, ii) constituting that the general balance criterion of bureaucracy is the internal molecular potential μm alternatively the temperature , iii) Elimination of disorientation between the within and external pressures of bureaucracy and subsystems, which did not identify the two types of strength carried by a particle of the fluid phase: the within energy of the molecule that is oscillatory and the external moving power which is on account of Brownian motion in the phase. We rectified accordingly the differential equatings of the usual thermodynamic potentials in addition to the Gibbs-Duhem equation. The request to the soil-water-air system is likely followed by some comments on the new fantasy of thermodynamic equilibrium shaping that emerges from this hypothesis.
Author(s) Details:
Erik Braudeau,
VALORHIZ,
R&D Department. 1900, Boulevard de la Lironde, PSIII, Parc Scientifique
Agropolis, F34980 Montferrier sur Lez., France.
Please see the link here: https://stm.bookpi.org/ACST-V1/article/view/11910
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