Friday 25 November 2022

Potentiometric Studies of Complex Equlibria of Ca, Mg and Zn with 5-Sulphosalicylic Acid in Cationic Micelles of CTAB: Experimental Investigation| Chapter 11 | Research Aspects in Chemical and Materials Sciences Vol. 4

 In differing compositions of cetyltrimethylammonium bromide (0.0, 0.5, 1.0, 1.5, 2.0, and 2.5% w/v), alloy ligand complex species of 5-sulphosalicylic acid accompanying CaII, MgII, and ZnII metal ions have been checked potentiometrically (CTAB). The experiment was conducted at 303 K while utilizing NaCl to maintain an ionic substance of 0.16 mol dm-3. The dynamic variety belongs to 5-sulphosalicylic acid are LH2- and LH2-. Based on statistical characteristics to a degree skewness, 2, Kurtosis, and crystallographic R-determinant, the best fit of complicated adaptive evolution has been chosen. The complexation of 5-sulphosalicylic acid accompanying metal ions developed in the formation of ML2H, ML2H2, and ML3H3 type complexes. On the support of electrostatic grounds, the change instability of complex species with surfactant arrangement has been described. The distribution of chemical variety with regard to pH and differing compositions of medium, as well as attainable complicated equilibria, is more investigated.

Author(s) Details:

M. Ramanaiah,
Department of Chemistry, Aditya Institute of Technology and Management, Tekkali-532201, India.

P. Seetharam,
Department of Chemistry, Lendi Institute of Engineering and Technology, Vizianagaram-535005, India.

M. Balakrishna,
Department of Chemistry, Lendi Institute of Engineering and Technology, Vizianagaram-535005, India.

B. Rama Raju,
Department of Chemistry, Aditya Institute of Technology and Management, Tekkali-532201, India.

S. Gouthamsri,
Department of Chemistry, Aditya Institute of Technology and Management, Tekkali-532201, India.

Please see the link here: https://stm.bookpi.org/RACMS-V4/article/view/8734


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