In the present work, the dissolution prevention of mild
steel induced by Indigofera tinctoria Leaves (ITL) extract was analysed using
different techniques such as weight loss, electrochemical impedance
spectroscopy and potentiodynamic polarisation in 1M HCl solution at various
contact periods and temperatures (303-333K). The result exhibits that Indigofera
tinctoria Leaves acts as a mild steel inhibitor that performs well in 1M HCl
solution. Inhibition efficiency of mild steel in 1M HCl increases as more
inhibitor is added. The Highest percentage of inhibition efficiency was found
to be 54.3% a 500 ppm concentration at a temperature of 303 K. Thermodynamic
parameters Ea, Qads, Gads, H, and S suggest that the adsorption of Indigofera
tinctoria leaves extract is exothermic, spontaneous, and a chemisorption
process. The Langmuir adsorption isotherm governs the adsorption of Indigofera
tinctoria leaves on a mild steel surface. Also, the electrochemical study
exhibits that it acts as a cathodic inhibitor in a 1M HCl medium. Thin film
formation on the surface of metal may also be confirmed by UV, FT-IR, and SEM
studies.
Author(s) Details
M. Prema
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002, Tamil Nadu, India.
S. Vidhya
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002, Tamil Nadu, India.
A. Leema Rose
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002, Tamil Nadu, India.
F. Janeeta Priya
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002, Tamil Nadu, India.
J. Morris Princey
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002, Tamil Nadu, India.
A. Arputharaj
St.Joseph's College Autonomous, Tiruchirappalli, India.
P. Aparna
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002,
Tamil Nadu, India.
T. R. Amsica
PG and Research Department of Chemistry, Holy Cross College (Affiliated to
Bharathidasan University), Tiruchirappalli–620002, Tamil Nadu, India.
Please see the book here :- https://doi.org/10.9734/bpi/cbrp/v9/7235
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