Copper (Cu) is a promising catalytic metal for C–C bond
construction through coupling transformations. Coupling strategies of a range
of organo-metallic reagents, with aromatic, heteroaromatic, and alkyl halides,
can be carried out by Cu-catalysts with high efficiency, demonstrating the
adaptability of Cu supported catalytic methods in carrying out these transformations.
Conversely, the parallel palladium-catalysed cross-coupling methods are
frequently complementary to the scope and selectivity of copper-assisted
methods. Furthermore, Cu-catalysts are displaying a distinct pattern of
reactivity that permits ligand-less coupling for the formation of
aromatic–heteroaromatic and heteroaromatic–heteroaromatic bonds, a
transformation that typically calls for unique, specially created ligands with
Pd-catalysts. Early findings in the field of Cu-mediated couplings to generate
C-C bonds are summarised in this chapter.
Author(s) Details
Gadamani Suresh Babu
Department of Humanities & Sciences, Brilliant Institute of Engineering
& Technology, Abdullapur (V), Abdullapurmet (M), R.R District-501505,
India.
Kiran Kumar Tatapudi
Discovery Analytical R&D Department, Aragen Life Sciences Pvt. Ltd.,
IDA Nacharam, Hyderabad, Telangana, India.
Surinderpal Singh
Department of Chemistry (H&S), CMR Engineering College, Kandlakoya (V),
Medchal Road, Hyderabad, Telangana 501401, India.
Tiruveedhula
Somasekhar
Department of Humanities & Sciences, Vidya Jyothi Institute of
Technology, Aziz Nagar Gate, Chilkur Balaji Road, Himayat Sagar Rd, Hyderabad,
Telangana 500075, India.
Hemambika SadasivuniDepartment
of Freshmen Engineering, St. Martin’s Engineering College, Dhulapally,
Hyderabad, Telangana-500100, India.
S. Ratna Kumari
Department of Chemistry, Basic Science & Humanities, Vignan's Nirula
Institute of Technology and Science for Women, Guntur, A.P., India.
S N Murthy Boddapati
Department of Chemistry, Sir C R Reddy College, Eluru, Andhra
Pradesh-534007, India.
Please see the book here :- https://doi.org/10.9734/bpi/cbrp/v9/6761
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