Monday, 1 September 2025

Narrowing the Gap between Anion and Strong Ion: A Current Perspective | Chapter 8 | Medical Research and Its Applications Vol. 10

 

Background: A true “ion gap” does not exist in vivo which makes the anion gap a fundamental tool to evaluate acid-base disorders. The strong anion gap (SIG), which is the foundation of the Stewart acid-base method, is a term that many doctors are unaware of, despite its significance in understanding acid-base pathophysiology. It is unknown how much the anion gap and the strong ion gap differ quantitatively.

 

Aim: The present study aimed to discuss narrowing the gap between the anion gap and the strong ion gap.

 

Methods: The quantitative difference between the SIG and the albumin-corrected anion gap (AGc) was calculated at a wide range of albumin, phosphorus and pH levels.

 

Results: At an albumin level of 1-3 g/dl and pH from 6.9-7.3, the contribution difference of albumin between the AGc and the SIG was maximally -0.97 to 0.51 mEq/L. In metabolic alkalosis and hypoalbuminaemia, the AGc differed less than 2 mEq/L from the SIG. The calculated contribution of phosphorus was higher in the SIG with phosphorus levels > 2 mmol/L and could be accounted for in the anion gap with the conversion factor 1.76x[phosphorus, in mmol/L].

 

Conclusion: The SIG and the AGc were nearly identical across a wide range of values, particularly when albumin and phosphorus levels were low. The anion gap would be more precise incorporating the major components of the SIG using the equation: [Na+] - [Cl-] - [HCO3-] - 2.5x[albumin, in g/dL] – 1.76x[phosphorus, in mmol/L], with an arbitrarily set reference range of 1 + 5 mEq/L. To have a better understanding of the pathophysiology and to be more accurate, the anion gap, or perhaps a more logical term, “the ion gap” should be written to become almost identical to the SIG.

 

 

Author(s) Details

Kenrick Berend

Department of Nephrology, Curacao Medical Centre, Curacao.

Andrew L. Lundquist

Division of Nephrology, Massachusetts General Hospital, Boston, MA, United States.

 

Please see the link:- https://doi.org/10.9734/bpi/mria/v10/998

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