By
way of radiation theory, the molecular tunnelling mechanism has been taken into
account. The formula for measuring entropy knowledge was obtained by means of a
thermal equilibrium radiation interaction model with a molecule at low
temperatures. For the low temperature plateau of unimolecular chemical reaction,
the physical value of information entropy was calculated. It is a measure of
the conversion of thermal radiation energy to mechanical energy during the
elementary activation act that transfers atoms in a molecule. It is also a
measure of uncertainty about this conversion of energy. The conversion takes
place at a temperature when the elementary activation act's average energy is
equal to a portion of the elementary activation act. The zero energy of the
molecule in transformation. There have been two unimolecular reactions
investigated. These are β-hemoglobin Fe-CO bond recombination and benzoic acid
dimer double proton transfer for sequential hydrogen bond deuteration and
various hydrostatic pressures. It is possible to determine its value in the energy
units of low-temperature plateau measurements using the information entropy
formula. Probabilities of reaction occurrence, efficacy and mean-square
fluctuations of the parameters of the distribution function They were also
determined. By using a distribution function, the proposed interaction model of
thermal equilibrium radiation with a molecule at low temperatures explains the
mechanism. The role represents a barrier of activation as the sub-conformation
states of the molecule are set. Both states share the shared function of
supplying the tunnelling mechanism with a portion of the energy of zero-point
vibrations.
Author(s) Details
Anatoly
V. Stepanov
National Ozone Monitoring Research and
Educational Centre, Belarusian State University, Kurchatov str. 7–816, 220045
Minsk, Belarus.
Department of Technical Physics, Information Technologies and Robotics Faculty, Belarusian National Technical University, B. Khmelnitsky str. 9, Building 11, 220013 Minsk, Belarus.
View Book :- https://bp.bookpi.org/index.php/bpi/catalog/book/349
No comments:
Post a Comment