Synthesis, Characterization and Crystal Structure of Mononuclear Bis(2-aminopyridine) Zinc Complex | Chapter 7 | Recent Developments in Chemistry and Biochemistry Research Vol. 7

In this paper, a simple one-pot synthesis, characterization and crystal structure of novel N-Zn complex is described. 1H and 13C NMR spectra were obtained using a Bruker AM-300 spectrometer. Infrared spectra were recorded on a Mattson Galaxy Series FTIR 3000 spectrometer. 2-Aminopyridine reacts with Zn(OAc)2·2H2O in alcohol and forms the mononuclear bis(2-aminopyridine)- zinc complex, whose structure was determined via X-ray diffraction analysis. The complex is also characterized by nuclear magnetic resonance (NMR) spectroscopy, infrared (IR) spectroscopy, mass spectrometry (MS), and elemental analysis. The crystal is a prism and has a spacegroup of P2(1)/n, with the following parameters: with a = 9.1914(8) Å, b = 13.8595(12) Å, c =13.2921(12) Å, α = 90.00 º, β = 92.474 º, γ = 90.00 º, λ =0.7103°, V = 1691.7(3), Z = 4, Dc = 1.459 g/cm3, Mr = 371.69 and F (000) = 768, R = 0.0416, wR = 0.0793 for 3689.

 

Author (s) Details

Luo Mei
Department of Chemical Engineering, Hefei University of Technology, Hefei-230009, P.R., China.

 

Tang Hai Ming
Department of Chemical Engineering, Hefei University of Technology, Hefei-230009, P.R., China.

 

Please see the book here:- https://doi.org/10.9734/bpi/rdcbr/v7/2729