The reaction between Thallium (III) and succinic dihydrazide
is carried out in a mixture of perchloric and hydrochloric acid medium. The
reaction proceeds through formation of complex with reactant, which decomposes
in subsequent steps to give product. Effect of acrylonitrile shows, that there
is no formation of free radicals. The increase in [H+] and [Cl-] decreases the
rate of the reaction. The increase in ionic strength does not affect the rate
of reaction. The effect of temperature was studied at four different
temperatures ranging from 15°C to 30°C. The activation parameters were also
determined and a mechanism is predicted
Author(s) Details
Dr. Amit Shrikant Varale
Department of Chemistry, A.S.P. College, Devrukh-415804, Dist-Ratnagiri, Maharashtra State, India.
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Book :- http://bp.bookpi.org/index.php/bpi/catalog/book/173Author(s) Details
Dr. Amit Shrikant Varale
Department of Chemistry, A.S.P. College, Devrukh-415804, Dist-Ratnagiri, Maharashtra State, India.
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