Synthesis and Characterization of 4-Chloro-2-(1-phenyl imino) Propyl Phenol and Its Metal Complexes | Chapter 2 | Novel Aspects on Chemistry and Biochemistry Vol. 3

 4-chloro-2-(1-phenyl imino) propyl phenol, a novel Schiff base ligand, has existed synthesized by condensing 5’-chloro-2’-hydroxy propiophenone accompanying aniline. Co (II), Ni (II), Cu (II) and Zn (II) complexes of the combined ligand have been prepared in the alcoholic medium. The ligand and allure complexes have been from various physicochemical methods which include drawing moment determination, bony object in mouth conductance plan, UV-vis, infrared and thermogravimetric studies. Magnetic moment dossier and spectral studies explained the octahedral arithmetic of metal composites, thermogravimetric analysis explained the warm stability of the complexes, IR and TGA studies habitual the presence of the related water molecules in the metal aggregates.

Author(s) Details:

S. S. Wagh,
Department of Chemistry, Adarsh Education Society’s Arts, Commerce and Science College, Hingoli, Maharashtra-431513, India.

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Recent Study on Synthesis, Characterization and Antimicrobial Activities of Some Transition Metal Complexes of Biologically Active Bidentate Ligands | Chapter 7 | Current Perspectives on Chemical Sciences Vol. 1

 

A new solid complexes of Mn(II) and Fe(III) complexes with bidentate Schiff base ligand derived from
2-amino 4,6 dihydroxypyrimidine and P- chlorobenzaldehyde, P-nitrobenzaldehyde have been
reported. The ligand and its complexes were screened for their antifungal and antibacterial activity
against Aspergillus niger, Penicillium chrysogenum, Fusarium moneliforme and Aspergllus flavus and
Escherichia coli. Salmonella typhi, Staphylococcus aurious, B. subtilis. The result indicated that the
complexes exhibited good antifungal and antibacterial activities. The Schiff base commonly
coordinates through the oxygen atom of phenolic OH group and the nitrogen atom of azomethine
group, which is confirmed by IR spectral data. Further conclusive evidence of the co-ordination of the
Schiff bases with the metal ions was shown by the appearance of new bands due to n(M-N) and n(MO) in the metal complexes.

Author(s) Details

Dr. D. T. Sakhare
U.G, P.G. & Research Centre, Department of Chemistry, Shivaji, Art’s, Comm. & Science College Kannad, 431103, (M.S.), India.

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