The
performance of the polymeric membranes depends on morphology and its strength.
The pressure-driven membrane separation process required good structural
strength and desired flux. But these parameters depend on the formation of the
right size pores, the number of pores & their distribution, and even wall
thickness in surface and cross-sectional morphologies of the membrane. The
desired values of the above decide the structural stability and permeate flux
of hollow fibre membrane(HFM). Obtaining the desired membrane morphology yields
the preferred strength and performance. In general, the characteristics of
membranes derived from the flow rate of the dope solution, the shear rate, the
composition of dope solutions, and the mass flux rate between solvent and
non-solvent at the coagulant bath during the spinning process. So, a steady
state simulation performed using the Computational Fluid Dynamics (CFD) tool to
understand the fluid flow behavior inside the angular spinneret and the results
correlated with the physio-structural parameters such as strength, morphology,
burst pressure of the hollow fiber Ultra Filtration (UF) membrane and its
formation. The study on the flow behavior of dope solution inside the spinneret
carried by various the power-law index value (0.3 < n <0.7) and the dope
solution flow rate (0.1< Q <1.2 mL/min). The flow profiles at the exit of
75o angular spinneret gave the delightful result of why the fiber membrane
unable to withstand the high-pressure application. Also, it is exbound that the
shear induced flow rate is struggle to drive some power-law index fluids and
resulted in bulk flow at some spot of exit of the spinneret and leaves the
hollow fiber membrane to form uneven wall thickness. The dope flow rate and the
power-law index values need to be optimized to understand the formation of UF
membrane morphology.
Author(s) Details:
Suresh K.,
Department
of Chemical Engineering, SRM Institute of Science and Technology,
Kattankulathur, Chennai, Tamil Nadu, India.
Selvam
K.,
Department
of Chemical Engineering, SRM Institute of Science and Technology,
Kattankulathur, Chennai, Tamil Nadu, India.
Karunanithi B.,
Department of Chemical Engineering, SRM Institute of Science and
Technology, Kattankulathur, Chennai, Tamil Nadu, India.
Please see the link here: https://stm.bookpi.org/TAER-V4/article/view/13100