Showing posts with label adsorption isotherm. Show all posts
Showing posts with label adsorption isotherm. Show all posts

Thursday, 21 October 2021

Kinetics and Isotherm Studies for Methylene Blue Dye Removal Using Carbon Derived from Bulb of Zephyranthes citrina | Chapter 10 | New Innovations in Chemistry and Biochemistry Vol. 4

 The primary goal of this study is to use kinetics and isotherm investigations to remove the methylene blue dye from wastewater samples using carbon generated from the Zephyranthes citrina (ZC) bulb. The current research takes a novel method by looking at porous, efficient raw carbon from ZC, which was used as an adsorbent. At a temperature of 900°C, the well-dried and finely powdered ZC bulb was carbonised. FT-IR, UV-visible, Scanning Electron Microscopy (SEM), and X-ray diffraction techniques were used to analyse the carbonised crude ZC sample, as well as their adsorption capacity to remove the basic methylene blue (MB) dye from an aqueous sample. Both adsorption isotherm and kinetic approaches are used in adsorption investigations. In the batch mode operation, different adsorbate concentrations and adsorbent amounts were used at different time intervals. The kinetics and adsorption process were evaluated using Lagergren first order, pseudo second order, and intra particle diffusion kinetic models. The findings revealed that the adsorption process follows Lagergren's first-order kinetic model. Based on the results, the highest dye removal (81%) was reached for methylene blue in a solution containing 50 mg of the 50 ml dye after 3 hours. The results showed that the ZC carbon bulb is an effective adsorption material that can also be utilised as a low-cost alternative to absorb dye from an aqueous solution without activation.

Author (S) Details

S. Vedanayaki
Department of Chemistry, Kandaswami Kandar’s College, Velur, Namakkal – 638 182, India.

J. Prakash
Department of Chemistry, Kandaswami Kandar’s College, Velur, Namakkal – 638 182, India.


View Book :- https://stm.bookpi.org/NICB-V4/article/view/4329

Wednesday, 8 September 2021

Removal of Dyes by using Rice Husk as Agricultural Solid Waste Adsorbent: Experimental investigation | Chapter 8 | Challenging Issues on Environment and Earth Science Vol. 7

Rice Husk (RH) Nano Activated Carbon (NAC) was used to remove methylene blue (MB) and black B (BB) colours from synthetic solutions in batch adsorption studies. Several operating factors, including pH (1-11), contact time (15-75 minutes), and temperatures, were evaluated for the two dyes of various concentrations (50-300 mg/l) (30-600C). At 30°C and pH 3 for MB and pH 11 for BB, the high adsorption capacity was achieved. The adsorption equilibrium was reached after 60 minutes. The findings of the determination of adsorption isotherms were analysed utilising the Isotherm models Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich The Freundlich and Langmuir isotherm models were both beneficial for MB dye, whereas Langmuir was exclusively beneficial for BB dye. Pseudo-first order and pseudo-second order kinetics were studied by the researchers. According to the data, the uptake rate of the NAC adsorbate followed a pseudo second order kinetic model for both colours.



Author (S) Details

Sara G. Abd-elnaeem
Chemical Engineer Division, Engineering Dept., National Research Center, Egypt.

Azza. I. Hafez
Chemical Engineer Division, Engineering Dept., National Research Center, Egypt.

Rania M. Sabry
Chemical Engineer Division, Engineering Dept., National Research Center, Egypt.

T. E. Shakinas
Engineering Division, Faculty of Engineering, Cairo University, Egypt.



View Book :- https://stm.bookpi.org/CIEES-V7/article/view/3060