Showing posts with label N2 afterglows. Show all posts
Showing posts with label N2 afterglows. Show all posts

Thursday, 19 February 2026

Plasmas Afterglows with N2 for Surface Treatments -Additional Results 2025 | Book Publisher International

 

The present book is especially focused on flowing plasmas and afterglow devices containing N2. The plasmas were produced by high-frequency (RF, microwaves) discharges at low gas pressures. The microwave plasmas with surfatron and surfaguide cavities are specifically studied.

 

The most relevant active species in the studied flowing plasmas are the atoms and radicals coming from dissociated molecules ( N2, H2, O2, CH4). There is an interest in rare gas–molecule mixtures to obtain plasmas with high-energy electrons in He and long plasmas residence times in Ar.

 

The N and O atom densities are obtained after NO titration and related to N2 emission spectroscopy by discussing two methods to determine the part of N+N recombination at the origin of the observed N2 radiative states. The other active species densities are obtained by the line ratio intensity method.

 

To obtain quantitative measurements of the active species densities, it has been compared the results of NO titration for N and O – atoms to laser induced fluorescence (LIF, TALIF) for N, O and H-atoms. These last sophisticated laser method has allowed to choose the appropriate kinetic reactions in the N2-H2 and N2-CH4 flowing afterglows.

 

The N, H, O and C-atoms, NH and CN radicals were studied for plasma chemistry and surface treatments. The nitriding of TiO2 thin films has been analysed in detail.

Author(s) Details

André RICARD
Laboratoire de Physique des Gaz et des Plasmas, Université Paris-Saclay, CNRS, 91.400 Orsay, France and Laplace, CNRS, Université Toulouse, 31077 Toulouse, France.

 

Please see the book here :- https://doi.org/10.9734/bpi/mono/978-81-999106-4-5

Tuesday, 1 April 2025

Density of N2 Active Species in N2 Dielectric Barrier Discharge Afterglows by Optical Spectroscopy at Atmospheric Gas Pressure | Chapter 12 | Plasmas Afterglows with N2 for Surface Treatments synthesis 2024

Dielectric Barrier Discharges (DBD) have been used to develop Cold Atmospheric Plasmas and more specifically nitrogen afterglows. The DBD afterglow has been investigated by emission spectroscopy from the VUV (200-300 nm) up to the near IR (1 μm) ranges. A kinetics scheme allowed to determine numerous N2 active species densities. The obtained densities decreased slowly in the afterglow time of (1- 10)10-3s with mean values of 1015 cm-3 for N- atoms, 1012 cm-3 for N2(A) molecules, 1011 cm-3 for O- atoms (coming from air in impurity) and 1010 cm-3 for N2(B,0) radiative molecules. The other excited species (N2(B,11), N2 (X,v>4), NO(X, A, B) and O1S.N2 were found at a lower density between 106 and 108 cm-3.

 

Author (s) Details

 

Frank Clément
Université de Pau et des Pays de l’Adour, E2S UPPA, CNRS, IPREM UMR 5254, 64600 Anglet, France.

 

Bernard Held
Université de Pau et des Pays de l’Adour, LEGP, F-64000 Pau, France.

 

André Ricard
LAPLACE, Université de Toulouse, CNRS, INPT, UPS, 118 route de Narbonne, 31062 Toulouse Cedex 9, France.

 

Please see the book here:- https://doi.org/10.9734/bpi/mono/978-93-49473-93-5/CH12