Assessment of Dielectric Parameters of Hydrogen Bonded Complexes: Tri-n-butyl Phosphate (TBP) with Aliphatic Alcohols Using Huysken–Craco, Palit and Onsager’s Methods | Chapter 11 | Fundamental Research and Application of Physical Science Vol. 6

 This episode investigates the complex formation of TBP in long chain alcohols namely., 1-hexanol, 1-heptanol, 1-octanol by following Huysken-Craco method, Palit plan and Onsager method. Dielectric studies of hydrogen-guaranteed compounds in non-polar solvents disclose vital analyses on the development of intermolecular composites in solution. Hydrogen bonds are a spellbinding type of molecular interplay that is essential in a type of fields, including pharmacology, allure, and molecular biology. The device of dipolar complexation involving TBP and three alcohols that is to say 1-hexanol, 1-heptanol, 1-octanol and in an apolar medium benzene, is investigated by three direct procedures viz.  Huysken–Craco, Palit and Onsager’s Methods utilizing dielectric measurement dossier at frequency 455kHz and at hotness 303.16 K. The interaction dipole moment, inferred polarisation, and apparent complex composition constant for the thermodynamically favorite stoichiometry of 1:1 complex are the parameters evaluated in these systems. It is decided that the complexation is predominantly on account of polarization effect including charge redistribution and the complex formation is most favoured in 1-hexanol system.

Author(s) Details:

S. K. Dash,
Deparment of Education in Science and Mathematics, Regional Institute of Education (NCERT), Bhubaneswar 751 022, Odisha, India.

T. Karunamoy,
Deparment of Education in Science and Mathematics, Regional Institute of Education (NCERT), Bhubaneswar 751 022, Odisha, India.

B. Dalai,
Department of Physics, School of Sciences, GIET University, Gunupur-765022, Odisha, India.

B. B. Swain,
Vivekananda Institute of Technology, Bhubaneswar 752054, Odisha, India.

Please see the link here: https://stm.bookpi.org/FRAPS-V6/article/view/10837